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(R)-(+)-2,2'-羟基--1,1'-联萘 |
2009-2-25 15:09:47 |
R-联萘酚
Product No.:SRCHEM0002
Description: (R)-(+)-1,1'-Bi-2-naphthol
Synonyms:
(R)-(+)-联萘酚
(R)-(+)-联二萘酚
(R)-(+)-1,1'-联-2-萘酚
(R)-(+)-2,2'-羟基--1,1'-联萘
(R)-(+)-1,1'-Bi(2-naphthol)
(R)-(+)-1,1'-Binaphthalene-2,2'-diol
(R)-(+)-2,2'-Dihydroxy-1,1'-dinaphthyl
(R)-(+)-BINOL
Structural Formula:
Molecular Formula: C20H14O2
Molecular Weight: 286.32
Linear Formula: HOC10H6C10H6OH
CAS Number: 18531-94-7
Beilstein Registry Number: 3616837
MDL number: MFCD00004068
PubChem Substance ID: 24854837
Application:
A chiral auxiliary used in the catalytic asymmetric
oxidation of sulfides to sulfoxides. Chiral lanthanide
triflates formed from binaphthol serve as catalysts
for asymmetric Diels-Alder reactions. Derivatives of
binaphthol have recently found use in asymmetric
Claisen rearrangements and asymmetric epoxidations.
The lithium aluminum hydride derivative of these
diols (BINAP-H) has been used extensively for the
reduction of ketones.
Standards:
Appearance: white crystalline powder
Chiral Assay(HPLC):ee: 99.5%ee+ ( optical purity)
Chemical Assay(HPLC): 99.5%+
optical activity：([a]22/D): +34°, c = 1 in THF
Melting Point: 208-210 °C (lit.)
Loss on drying: 0.05%
Chiral Assay:ee.
High-performance liquid chromatography(HPLC)
HPLC(Chiral Column):
Chemical Assay:
High-performance liquid chromatography(HPLC)
HPLC(C18.Column)
Packaging specifications:
Cardboard drum Packaging:
5kgs/ drum. 10kgs/ drum. 20kgs/ drum. 25kgs/ drum
:Reagent Packaging:
100g/ Bottle. 500g/ Bottle. 1kgs/ Bottle.
FT-IR Condensed Phase
Safety:
F: 10
Hazard Codes: T
Risk Statements: 25-36
Safety Statements: 26-45
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: DU3106100
References:
Merck: Merck13,1226
Fieser: Fieser12,190
Fieser13,113
Fieser15,135
Fieser16,132
Fieser17,116
Reference: Aldrich MSDS1, 189:B
Corp MSDS1(1), 414:B
FT-IR2(2), 1896:D
FT-IR1(1), 1111:A
RegBook1(1), 1303:I
Sigma FT-IR1(2), 323:A
Structure Index1, 199:C:2
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